I have made a few molds for silicone prosthetics with aluminum filled urethane from BJB called TC 1630. Great stuff. Freeman now has a product called Repro that is supposed to be the same thing, except better.
Polytek has some OK urethanes, but the viscosity is not what I would hope for. Also, the ones I have used are great for casting but set too fast to be used for molds that need to be built up. They would work alright for cast mold, meaning I build a wall and just pour the urethane in. But that only really works for smaller snaps, things like cheeks, or noses, or lips, or eyes.